Little exchange at the liquid/solid interface: defect-mediated equilibration of physisorbed porphyrin monolayers.
نویسندگان
چکیده
The transition from low to high density 2D surface structures of copper porphyrins at a liquid/solid interface requires specific defects at which nearly all exchange of physisorbed molecules with those dissolved in the supernatant occurs.
منابع مشابه
Supramolecular chemistry at the liquid/solid interface probed by scanning tunnelling microscopy
The liquid/solid interface provides an ideal environment to investigate self-assembly phenomena, and scanning tunnelling microscopy (STM) is one of the preferred methodologies to probe the structure and the properties of physisorbed monolayers on the nanoscale. Physisorbed monolayers are of relevance in areas such as lubrication, patterning of surfaces on the nanoscale, and thin film based orga...
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 34 شماره
صفحات -
تاریخ انتشار 2011